3 ms·
I'd say it's 3D in the sense that it's a height map rather than a cross section. (We've been able to see cross-sectional images of bonds for some time using tra
by hughprime 17y ago
I'd say it's 3D in the sense that it's a height map rather than a cross section. (We've been able to see cross-sectional images of bonds for some time using transmission electron microscopy, I think). It's not a full three-dimensional structure though, and it'd only work on flattish molecules like this.
It should be noted that this sort of resolution has been attainable for some time using scanning tunneling microscopy, but I'm pretty sure this is a first for atomic force microscopy. STM doesn't give you a very good image of bonds -- in fact bonds are generally the thing you _don't_ see, since STM works by pulling electrons in/out and bonds are stable places where electrons really don't want to come out of or go into. AFM, on the other hand, shows bonds very nicely.
You can sorta make out where the aromatic rings are. I'm not sure why it's so bright at the ends -- any organic chemists out there who can explain that?
- graphene 17y agoabout the brightness at the ends - I'm pretty sure that is due to the fact that this is a pi-conjugated system; that is, the pi-bonded electrons can jump around the whole molecule. This, together with the fact that the molecule is finite in size, means that the pi electrons are confined to a rectangle of lower potential energy, and when you solve the quantum mechanics (similarly to the quantum harmonic oscillator) you'll find higher electron density at the edges of the confining potential.
- hughprime 17y agoI'm totally willing to trust the word of someone called "graphene" on this one.