It seems like it would be more grid efficient to use more power at 3-5pm to cool your house to temperature early while solar is still high in availability then

It seems like it would be more grid efficient to use more power at 3-5pm to cool your house to temperature early while solar is still high in availability then to rush and cool from 5-6 when you get home. The current rate structure for anyone not paying spot rate does not incentivize that of course.