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plasticizers are a component of plastic, characterizing one ingredient in plastic as an 'additive' in order to shift the blame from plastic to plastic ingredien

plasticizers are a component of plastic, characterizing one ingredient in plastic as an 'additive' in order to shift the blame from plastic to plastic ingredients doesn't change the basic fact that plastics are endocrine disruptors because they leach plasticizer into food.

philipkglass 4y ago
Not all plastics contain plasticizers, so I would say that fnordpiglet is correct. For example, low density polyethylene (commonly used for jugs holding milk and water) is flexible without addition of any plasticizers. For this reason it is also used in laboratory equipment where plasticizer contamination would interfere with experiments: Low density polyethylene (LDPE) is a high molecular weight polyolefin material. Like all polyolefins, LDPE is nontoxic, non-contaminating and exhibits a high degree of break resistance. The polymerization of polyethylene results in an essentially straight chain, high molecular weight hydrocarbon. The polyethylenes are classified according to the relative degree of branching (side chain formation) in their molecular structures, which can be controlled with selective catalysts. LDPE has more side branching than HDPE resulting in a less-dense 3-D structure. As a result, LDPE is naturally very flexible without the addition of plasticizers and melts at a relatively low temperature (85°C). https://www.thermofisher.com/us/en/home/life-science/lab-plasticware-supplies/plastic-material-selection/low-density-polyethylene-ldpe-labware.html https://www.thermofisher.com/us/en/home/life-science/lab-pla...
- fnordpiglet 4y ago
  You should say I’m correct more often, then I can reference that for my wife’s benefit.
fnordpiglet 4y ago
Just because plasticizer has the word in its name doesn’t make it plastic. Nylon, PLA, PET, ABS, these are plastics. As far as I can tell they are not endocrine disruptors, and they are polymers - aka plastics. They require no other “ingredients” and can be used in an unadulterated form for many applications. Phthalates are monomers (aka not plastics) that are added to plastics to change physical properties of a plastic, such as flexibility, durability, make them more transparent, etc. They’re in fact derived from alcohols to my memory, and have no relationship to plastic. But they are also called plasticizers because they make plastics behave more “plastic” (in the adjective sense not the chemical sense). They are also suspected of being endocrine disruptors. But they’re not “plastic ingredients” - their use is optional and there exist alternatives. It is in fact an important distinction. There are other plasticizers that are not biologically active that can be used in place. Or, plasticizers don’t need to be used at all. Both of these options make the plastics benign. It’s an important distinction because plastic isn’t the problem at all, it’s the regulatory framework around plastic additives, none of which are strictly necessary and there are almost always safer alternatives. Plus it’s important to distinguish because it’s simply false to say plastics are a an endocrine disruptor when they aren’t, even if it’s convenient to get your point across.
- klipt 4y ago
  Right but in the absence of regulation, I would treat with suspicion e.g. fast food in any plastic container (or waterproofed "paper" container which usually means a plastic layer too). I consider glass, stainless steel, and cast iron safe, and try to avoid almost anything non stick or plastic for cooking/food storage.
  - fnordpiglet 4y ago
    In the absence of regulation I see no reason to believe that metal is stainless steel, that glass is unadulterated, or that iron doesn’t have toxic metals mixed in. I would focus energy on advocating for regulation unless you smelt your own metals. Edit: I’d be much more afraid of heavy metals from low quality steel, glass, and iron than modern plastic additives. Food grade plastics are heavily regulated, but metals and glass not really outside of a medical setting.
    - klipt 4y ago
      Toxic metals have been understood for a while so I would hope they are better regulated. Plasticizers are clearly not well regulated yet, "BPA free" stuff just uses BPS which is just as bad.
      - fnordpiglet 4y ago
        Hope isn’t a strategy.
  - fnordpiglet 4y ago
    PTFE (nonstick coating marketed under Teflon) is safe unless you inhale a lot of its fumes by heating it to over 500F. And by a lot I mean cases of fume fever show up with people welding lots of ptfe. You are probably thinking of Perfluorooctanoic acid, which is carcinogenic but most exposure happens from fabric coatings. It was banned in the US in 2013 and none of it is manufactured or used in the US currently. Which is an example of regulation of additives to plastics. The plastic itself (PTFE) isn’t the problem, it’s the additives. I’d point out interestingly PTFE is what Goretex is made out of. You heat PTFE then jerk it hard and it foams into a fabric.

philipkglass 4y ago

Not all plastics contain plasticizers, so I would say that fnordpiglet is correct. For example, low density polyethylene (commonly used for jugs holding milk and water) is flexible without addition of any plasticizers. For this reason it is also used in laboratory equipment where plasticizer contamination would interfere with experiments: Low density polyethylene (LDPE) is a high molecular weight polyolefin material. Like all polyolefins, LDPE is nontoxic, non-contaminating and exhibits a high degree of break resistance. The polymerization of polyethylene results in an essentially straight chain, high molecular weight hydrocarbon. The polyethylenes are classified according to the relative degree of branching (side chain formation) in their molecular structures, which can be controlled with selective catalysts. LDPE has more side branching than HDPE resulting in a less-dense 3-D structure. As a result, LDPE is naturally very flexible without the addition of plasticizers and melts at a relatively low temperature (85°C). https://www.thermofisher.com/us/en/home/life-science/lab-plasticware-supplies/plastic-material-selection/low-density-polyethylene-ldpe-labware.html https://www.thermofisher.com/us/en/home/life-science/lab-pla...

fnordpiglet 4y ago
You should say I’m correct more often, then I can reference that for my wife’s benefit.

fnordpiglet 4y ago

Just because plasticizer has the word in its name doesn’t make it plastic. Nylon, PLA, PET, ABS, these are plastics. As far as I can tell they are not endocrine disruptors, and they are polymers - aka plastics. They require no other “ingredients” and can be used in an unadulterated form for many applications. Phthalates are monomers (aka not plastics) that are added to plastics to change physical properties of a plastic, such as flexibility, durability, make them more transparent, etc. They’re in fact derived from alcohols to my memory, and have no relationship to plastic. But they are also called plasticizers because they make plastics behave more “plastic” (in the adjective sense not the chemical sense). They are also suspected of being endocrine disruptors. But they’re not “plastic ingredients” - their use is optional and there exist alternatives. It is in fact an important distinction. There are other plasticizers that are not biologically active that can be used in place. Or, plasticizers don’t need to be used at all. Both of these options make the plastics benign. It’s an important distinction because plastic isn’t the problem at all, it’s the regulatory framework around plastic additives, none of which are strictly necessary and there are almost always safer alternatives. Plus it’s important to distinguish because it’s simply false to say plastics are a an endocrine disruptor when they aren’t, even if it’s convenient to get your point across.

klipt 4y ago
Right but in the absence of regulation, I would treat with suspicion e.g. fast food in any plastic container (or waterproofed "paper" container which usually means a plastic layer too). I consider glass, stainless steel, and cast iron safe, and try to avoid almost anything non stick or plastic for cooking/food storage.
- fnordpiglet 4y ago
  In the absence of regulation I see no reason to believe that metal is stainless steel, that glass is unadulterated, or that iron doesn’t have toxic metals mixed in. I would focus energy on advocating for regulation unless you smelt your own metals. Edit: I’d be much more afraid of heavy metals from low quality steel, glass, and iron than modern plastic additives. Food grade plastics are heavily regulated, but metals and glass not really outside of a medical setting.
  - klipt 4y ago
    Toxic metals have been understood for a while so I would hope they are better regulated. Plasticizers are clearly not well regulated yet, "BPA free" stuff just uses BPS which is just as bad.
    - fnordpiglet 4y ago
      Hope isn’t a strategy.
- fnordpiglet 4y ago
  PTFE (nonstick coating marketed under Teflon) is safe unless you inhale a lot of its fumes by heating it to over 500F. And by a lot I mean cases of fume fever show up with people welding lots of ptfe. You are probably thinking of Perfluorooctanoic acid, which is carcinogenic but most exposure happens from fabric coatings. It was banned in the US in 2013 and none of it is manufactured or used in the US currently. Which is an example of regulation of additives to plastics. The plastic itself (PTFE) isn’t the problem, it’s the additives. I’d point out interestingly PTFE is what Goretex is made out of. You heat PTFE then jerk it hard and it foams into a fabric.