3 ms·
> The absolute zero macrostate includes all configurations of particles that will cause the thermometer to read 0. The probability of this macrostate occuring i
by kgwgk 4y ago
> The absolute zero macrostate includes all configurations of particles that will cause the thermometer to read 0. The probability of this macrostate occuring is quite low.
"Let's say those balls all have a random initial velocity at a random direction but all those balls are initially positioned near one corner in the cube. Thus the balls from a position stand point start with low entropy."
In every single initial configuration the particles will be at some distance from the thermometer and will cause it to read 0 according to you reasoning (until some time passes). I guess they all correspond to the same "absolute zero macrostate".
What I still don't see is how do you calculate the entropy using Gibbs entropy formula in such a way that the entropy is lower or higher for some initial configuration depending on the position of the particles. Gibbs entropy is not a property of the microstate - it's a property of the macrostate.