2 ms·
Traditional methane-to-methanol with carbon monoxide intermediate (based on steam reforming of natural gas): CH4 + H2O → CO + H2 CO + 2 H2 → CH3OH Direct red
by photochemsyn 4y ago
Traditional methane-to-methanol with carbon monoxide intermediate (based on steam reforming of natural gas):
CH4 + H2O → CO + H2
CO + 2 H2 → CH3OH
Direct reduction of CO2 to methanol without going through the methane, an already established technology (Fischer-Tropsch type chemistry):
CO2 + 3H2 → CH3OH + H2O
Methanol is a common feedstock for further chemical synthesis (such as making high-octane gasoline), so this is an option for fuels from direct air capture of carbon dioxide & electrolysis of water for hydrogen. Two methanol molecules are dehydrated to form dimethyl ether (CH3-O-CH3) as the initial step:
> "Methanol can be used to make a gasoline product. The process uses a special zeolite catalyst with pore size such that molecules up to C10 can get out of the catalyst. Larger molecules cannot be made with this process; therefore, a product is made with no carbon molecules greater than C10, which boils in the gasoline range. In this process, aromatics and branched-chain alkanes are made, which means the MTG process produces very high octane gasoline. Gasoline is the only product."
https://www.e-education.psu.edu/egee439/node/679 https://www.e-education.psu.edu/egee439/node/679
- adrian_b 4y agoBesides being relatively easy to convert into a gasoline product, methanol is also a convenient fuel for fuel cells, for direct conversion with high efficiency into electrical energy. When used for fuel cells, methanol does not have the storage problems of hydrogen, even if any equipment using methanol must be designed carefully, to avoid any leaks, which are dangerous because methanol is toxic and may cause blindness when ingested or absorbed through the skin.