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The article doesn't really make any sense. They seem to be talking about a sort of non-linear absorption of the laser light, so that above some critical intens
by ncmncm 5y ago
The article doesn't really make any sense.
They seem to be talking about a sort of non-linear absorption of the laser light, so that above some critical intensity that is found only close enough to the focal point of a converging laser beam, something suspended in the resin is triggered to absorb the red and ?? emit blue light, the which causes a chemical reaction in the surrounding resin at just that point, curing it.
Looking at the paper, they talk about red light producing excitons in one material that become triplets of "annihilator excitons" in another bit attached to it, and, with enough intensity, a pair of such triplets that will "fuse" to make a single "hot" exciton, which decays emitting a blue photon. Presumably at lower intensity you get only one triplet at a time which hasn't enough energy to emit the critical blue photon. The suspended particles must be much smaller than the 637 nm red wavelength.
You would still need to build up the object from the inside out, or conventionally bottom up, unless the cured bits pass light exactly the same as the uncured resin. They also seem to suggest that if the resin is especially gelatinous, a cured bit does not move while other bits are being cured, so you don't need the sacrificial support structures.
Presumably, since nothing in the system moves except the light source, you should be able to make this work faster than one that has to add layers of resin.
The bit that catches the red photons seems to be a porphyrin cage around a palladium ion. So you trap some amount of palladium in each article produced. Getting suspended particles to hold together (in a silica shell) but disperse without clumping was its own challenge.
- q845712 5y agoit's possible that you're missing the trick of "two photon excitation" which the paper sort of breezes past, but is the solution for "i only want the effect to happen right where i've created a tiny focal sphere of this laser." see e.g. https://en.wikipedia.org/wiki/Two-photon_excitation_microscopy https://en.wikipedia.org/wiki/Two-photon_excitation_microsco... The triplets described in this paper seem to build on the "standard" 2P effect.
- ncmncm 5y agoThe "two photon excitation" they talk about seems to refer to a different, altogether slower process that requires many orders of magnitude higher intensity light, and has to go very, very slowly so as not to vaporize the resin by putting energy in too fast for it to diffuse away.