6 ms·
Calcium tartrate is a great high speed introduction to crystal growing because it is very forgiving and "magical." You can get ~millimeter size crystals in seco
by philipkglass 5y ago
Calcium tartrate is a great high speed introduction to crystal growing because it is very forgiving and "magical." You can get ~millimeter size crystals in seconds. Then once you're hooked you can try growing crystals that require more patience/technique. If you ever saw the demonstration of lead (II) iodide precipitating from solution [1], this demonstration looks similar except that the crystals are sparkly and colorless instead of sparkly and golden.
You'll need potassium hydrogen tartrate (cream of tartar), sodium hydrogen carbonate (baking soda), and calcium chloride (sold as DampRid or Pickle Crisp).
Add a spoon full of baking soda and a spoon full of cream of tartar to a glass of distilled water. They should fizz together as the baking soda neutralizes the acidity of the cream of tartar, releasing CO2. This is what you want, since the mixed neutral salt of tartaric acid is more soluble in water. Stir and wait for the fizzing to die down, then gradually stir in small portions of more cream of tartar until the additions stop dissolving. Let the solids settle in the glass.
Meanwhile, dissolve a spoon full of calcium chloride in a second glass of water. It should dissolve readily with a bit of stirring.
Once residual solids have settled in glass one, decant the clear liquid into another glass.
Now pour the clear decanted liquid into the calcium chloride solution with stirring. Within seconds, you should see sparkling needles rain out of the solution. These are your crystals. The transition is especially striking in direct sunlight. The crystals can be saved and seem to remain stable in air regardless of ambient humidity.
I unfortunately have not seen this demonstration written down elsewhere so I can't offer a citation. I came to it by personal experience when I was on a crystal growing kick as a kid. (Though it may well have been written down somewhere that I have never come across.)
[1] Like in this video: https://www.youtube.com/watch?v=AO67MnZaAvQ https://www.youtube.com/watch?v=AO67MnZaAvQ
- BuildTheRobots 5y agoDo you know how safe the resulting crystals are to handle?
- philipkglass 5y agoI believe that they are safe to handle. None of the compounds or elements involved are toxic at moderate doses even if ingested. I personally handled these crystals with bare hands many times.
- errcorrectcode 5y ago> with bare hands many times. That's how my dad and grandfather both contracted a very specific benign bladder cancer. From having their hands in a solvent without gloves. ):
- 0des 5y agoJust curious, which solvent?
- errcorrectcode 5y agoIt was likely MEK or maybe toluene. They had their hands in everything and had to scrub them at the end of the day with pumpice, but the grease never came out completely.
- kragen 5y agoIf you rub them in your eyes hard enough, you can badly injure your corneas. Maybe if you're really creative you can find some other way to damage yourself with them, but that's all I can think of. Tartaric acid can be toxic at 2000 mg/kg or so, but calcium tartrate is much less soluble, so even much larger doses are probably safe.
- drran 5y agoSearch for «Rochelle salt piezoelectric crystals».
- fuzzfactor 5y agoHere's a project where Rochelle salt can be crystallized to get a piezo effect. http://srjcstaff.santarosa.edu/~yataiiya/E45/PROJECTS/Homebrew%20Piezoelectric%20Crystal.pdf http://srjcstaff.santarosa.edu/~yataiiya/E45/PROJECTS/Homebr... The sodium carbonate needed is otherwise known as "washing soda" in addition to being called "soda ash".
- huhtenberg 5y agoPotassium bitartrate is also a great introduction to crystals. Get a bottle of good red wine, 2010 or thereabouts. Uncork and drink it. Now look at the bottom of the last glass, if you still can, and - voila - potassium bitartrate. If you don't find any, don't despair and try another bottle.
- MontagFTB 5y agoFinally some instructions I can follow!