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The 1000x efficiency headline is from Figure 4 of the source PDF: https://advances.sciencemag.org/content/advances/7/23/eabe4206.full.pdf https://advances.scie
by LeifCarrotson 5y ago
The 1000x efficiency headline is from Figure 4 of the source PDF:
https://advances.sciencemag.org/content/advances/7/23/eabe4206.full.pdf https://advances.sciencemag.org/content/advances/7/23/eabe42...
Units are Amps per miliwatt on the Y axis and electron volts on the X axis. The black BTO line has a minimum of around 1x10^-10 at 2.8 eV, which is the energy of a photon in 450 nm blue light, and the red SBC222 line has a minimum of around 1x10^-7. Yes, the difference between 10^-10 and 10^-7 is 1000x; good job, headline! But no, that's not the key takeaway from the article.
Solar cells have an efficiency curve based on their bandgap and the energy in the incident light. It's theoretically a straight line, and regular silicon cells get pretty close to it, see the figure here:
https://www.pveducation.org/pvcdrom/solar-cell-operation/spectral-response https://www.pveducation.org/pvcdrom/solar-cell-operation/spe...
Note the units in A/W, not A/mW, also, the research is at a temperature of 77k, the boiling point of liquid nitrogen, while the above plot is close to room temperature. At 450 nm = 2.a silicon cell produces about 0.35 x 10^-3 A/mW, which represents an efficiency of something like 30% in the real world.
This research and that figure 4 plot fundamentally show that conventional barium titanate = BaTiO3 = BTO, produces very little energy from 450 nm light. The researchers fixed this problem with a multilayer cell using strontium titanate, SrTiO3, or STO, then BTO, then calcium titanate, CaTiO3 or CTO, in an STO_2/BTO_2/CTO_2 crystal lattice stack. That's the breakthrough result; they were able to bridge this gap in energy output and take in more wavelengths of visible light.
The actual efficiency of the starting point was about a million times worse than a good silicon cell. There's plenty of room for improvement when you start that low! The end result is still on the order of a thousand times worse than a silicon cell. A production dye-sensitized solar cell today reaches about 10% efficiency, a monocrystaline silicon cell gets about 22%, but the DSSC has potential to be much cheaper to produce, can be flexible, and is not as well understood. This research may help to close that efficiency gap.
- MichaelZuo 5y agoA 1000x improvement on a baseline 1000000x worse makes sense. I was wondering for a bit how a PV cell could break conservation of energy. The article has quite a clickbait title.
- tomcam 5y agoThat explanation was a tour de force. Thank you. You’ve done your good deed for the day!
- wiz21c 5y agoI absolutely don't understand all the physics but are "barium titanate" and "strontium titanate" rare stuff ?
- tedsanders 5y agoNo. Depends on your definition of rare, of course. You can see prices for various formulations and purities if you Google. Strontium titanate is used for jewelry, as it was one of the main diamond simulants back before cubic zirconia. I did my PhD working with crystals of strontium titanate and contributed to two Wikipedia articles on it. Looking at the elemental abundances you can see that titanium and strontium are fairly high, above both gallium and arsenic, another solar cell pair. Barium is in the ballpark of gallium and arsenic. https://en.m.wikipedia.org/wiki/Abundance_of_the_chemical_elements https://en.m.wikipedia.org/wiki/Abundance_of_the_chemical_el...
- jacquesm 5y agoAny multi junction cells do considerably better than that 22%: https://en.wikipedia.org/wiki/Multi-junction_solar_cell https://en.wikipedia.org/wiki/Multi-junction_solar_cell
- Teknoman117 5y agoI wonder what the difference in energy demands for producing them are.
- AtlasBarfed 5y agoI do see that a ferroelectric perovskite can do 22%. Maybe this could be the outer protective layer for the perovskite cell. Isn't the main perovskit engineering issue the degradation when exposed to the atmosphere? Ferroelectric seem to do other interesting thing, like harvest from ultraviolet, and exhibit some "bulk effects" that exceed "theoretical" maximums, but obviously none of that has been found to make a usable commercial cell. I hope PV research is still being aggressively funded. It seems to me that solar cell costs could be dropped another 50-75% under silicon with the right combination of perovskite and other materials. The future of our climate hinges on it.