That original print will probably be worthless as people will regard it as a copy. You'd also be up against life ruining fraud charges. But yes there are ways

That original print will probably be worthless as people will regard it as a copy. You'd also be up against life ruining fraud charges. But yes there are ways to link NFTs to products. Louis Vuitton and Nike are linking NFTs to their products with things like built-in NFC tags and QR codes plus other probably more secretive things.