You can add them to RAID0/1 vdevs; you can't add them to RAIDZ vdevs. Which you don't have if you don't run ZFS. You might have RAID5, but then you also have

You can add them to RAID0/1 vdevs; you can't add them to RAIDZ vdevs. Which you don't have if you don't run ZFS. You might have RAID5, but then you also have a write hole.