4 ms·
For simple organic reactions, the shape of benzene [0] matters. Benzene has its quirky ring shape thanks to pi bonds [1], which only make sense in a 3D orbital
by Kednicma 6y ago
For simple organic reactions, the shape of benzene [0] matters. Benzene has its quirky ring shape thanks to pi bonds [1], which only make sense in a 3D orbital model. The planetary model already has trouble with benzene formation and reactions. Another good example is water, whose hydrogen atoms are physically positioned almost entirely within the oxygen atom, according to the planetary model. Water's actual orbitals [2] have massive "echo" interactions on the hydrogen sides, which "push" the electrons onto one side of the molecule. Doing this with orbital mechanics alone would be, at a minimum, a headache.
The essential main problem with the planetary model is in the word "planetes" or "wanderer"; electrons are not exactly point charges whizzing about the nucleus at high speed (although they kind of are, because of gold's color and other properties) but more like smeared-out across an orbital. Think of soft electron-butter being spread by a galactic butter knife.
[0] https://en.wikipedia.org/wiki/Benzene https://en.wikipedia.org/wiki/Benzene
[1] https://en.wikipedia.org/wiki/Pi_bond https://en.wikipedia.org/wiki/Pi_bond
[2] http://www1.lsbu.ac.uk/water/h2o_orbitals.html http://www1.lsbu.ac.uk/water/h2o_orbitals.html