3 ms·
In a similar vein, https://blogs.sciencemag.org/pipeline/archives/2010/02/23/things_i_wont_work_with_dioxygen_difluoride https://blogs.sciencemag.org/pipeline/a
by tempguy9999 7y ago
In a similar vein, https://blogs.sciencemag.org/pipeline/archives/2010/02/23/things_i_wont_work_with_dioxygen_difluoride https://blogs.sciencemag.org/pipeline/archives/2010/02/23/th...
"At seven hundred freaking degrees, fluorine starts to dissociate into monoatomic radicals, thereby losing its gentle and forgiving nature."
further on
"The paper goes on to react FOOF [dioxygen difluoride] with everything else you wouldn’t react it with: ammonia (“vigorous”, this at 100K), water ice (explosion, natch), chlorine (“violent explosion”, so he added it more slowly the second time), red phosphorus (not good), bromine fluoride, chlorine trifluoride (say what?), perchloryl fluoride (!), tetrafluorohydrazine (how on Earth...), and on, and on. If the paper weren’t laid out in complete grammatical sentences and published in JACS, you’d swear it was the work of a violent lunatic."
- EdwardCoffin 7y agoAnd who could forget: "But I have to admit, I’d never thought much about the next analog of hydrogen peroxide. Instead of having two oxygens in there, why not three: HOOOH? Indeed, why not? This is a general principle that can be extended to many other similar situations. Instead of being locked in a self-storage unit with two rabid wolverines, why not three?" [1] [1] https://blogs.sciencemag.org/pipeline/archives/2014/10/10/things_i_wont_work_with_peroxide_peroxides https://blogs.sciencemag.org/pipeline/archives/2014/10/10/th...
- ethbro 7y agoA lot of the articles make me wonder if the labs that do highly reactive work are staffed by people who thought EOD jobs were too quiet.