The wavelengths that are furthest apart are red and violet. Which perceptually are close together, for red-green blind as well. But what does matter is picking

The wavelengths that are furthest apart are red and violet. Which perceptually are close together, for red-green blind as well. But what does matter is picking the colors based on the corresponding receptors' peak sensitivity. The L receptors are most sensitive to red, and the S receptors to blue, so in that sense you're right. (Red-green blind or weak people lack the M receptors of have anomalous versions, respectively.)