But Unix didn't adopt everything-is-colon-separated-values. Everything being unstructured text leads to a lot of different, incompatible ways of structuring tha

But Unix didn't adopt everything-is-colon-separated-values. Everything being unstructured text leads to a lot of different, incompatible ways of structuring that text. S-expressions themselves aren't important, I think, it's just having some standard structure that's used everywhere and you don't have to parse yourself. Trees are a good choice for a universal structure, hence things like XML. S-expressions are just a very lightweight and flexible format.