3 ms·
Hi, I am afraid I won't dig into this now due to time reasons (I have to go back and read up stuff), but I just would like to give a remark regarding the conce
by wuschel 10y ago
Hi,
I am afraid I won't dig into this now due to time reasons (I have to go back and read up stuff), but I just would like to give a remark regarding the concept you have sketched out:
The different states you describe do not have to be on different energy levels. A catalyst provides an alternative reaction mechanism that might have a different activation energy. It can result in a molecule of similar energy state, and, yes, you can have a reaction towards an energetically higher state.
I am sure there is many a publication that models the electronic transitions that occurs when gas molecules react with metals. Funky stuff, which involves number crunching with models of atomic/molecular orbitals or bands, and even more funky spectroscopic real time measurements of reactions.
Chemistry has gone a long way since alchemy, and there are many abstraction layers to get through if you want to have an explanation that would satisfy a physicists. At the end, you will move from empirical knowledge towards a world of quantum chemistry/physics. That is the beauty (or curse) of the discipline that is chemistry.
Now, if you are curious how such a thing works, I suggest look up the "Wilkenson catalyst" (a Rhodium based catalytic hydrogenation agent) as an example. It gives you an idea how organometallic compounds work at various levels of depth.
- avmich 10y ago> and, yes, you can have a reaction towards an energetically higher state. Where does that extra chemical energy come from? Other degrees of freedom of a molecule? In general, I'd expect the reaction H2 -> 2H+ + 2e- not to be anything like dominant. It's the separation of charges which is the source of energy of the cell, and the energy is released along the path of those charges recombining. Or am I missing something here? > there are many abstraction layers to get through if you want to have an explanation that would satisfy a physicists. Yes, I'm interested in the actual physics of the process, not in the net chemical result...