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You're thinking of the Argonne research from Jan, that used iridium to create a closed lithium air battery. They used the iridium to prevent lithium peroxide fr
by rgbrenner 10y ago
You're thinking of the Argonne research from Jan, that used iridium to create a closed lithium air battery. They used the iridium to prevent lithium peroxide from forming and clogging the pores of the electrode.
http://www.anl.gov/articles/stable-superoxide-opens-door-new-class-batteries http://www.anl.gov/articles/stable-superoxide-opens-door-new...
This research from MIT is entirely different. It doesn't use iridium at all.
It's actually quite interesting how they solved this problem (in comparison to Argonne's approach). To quote the press release:
The secret to the new formulation is creating minuscule particles, at the nanometer scale (billionths of a meter), which contain both the lithium and the oxygen in the form of a glass, confined tightly within a matrix of cobalt oxide. The researchers refer to these particles as nanolithia. In this form, the transitions between LiO2, Li2O2, and Li2O can take place entirely inside the solid material, he says.
The nanolithia particles would normally be very unstable, so the researchers embedded them within the cobalt oxide matrix, a sponge-like material with pores just a few nanometers across. The matrix stabilizes the particles and also acts as a catalyst for their transformations.
http://news.mit.edu/2016/new-lithium-oxygen-battery-greatly-improves-energy-efficiency-longevity-0725 http://news.mit.edu/2016/new-lithium-oxygen-battery-greatly-...
http://li.mit.edu/Archive/Papers/16/Zhu16KushimaNatureEnergy.pdf http://li.mit.edu/Archive/Papers/16/Zhu16KushimaNatureEnergy...
- tim333 10y agoAlso this battery isn't Lithium-air in spite of the the Economist having that as a title.
- deleted 10y ago[deleted]
- rincebrain 10y agoApparently, "lithium-air" is a term for lithium-oxygen batteries, not solely those relying on ambient oxygen. While the MIT news writeup only refers to other batteries using "lithium-air", the ANL press release refers to it as "a lithium-air battery". [1] [2] So while lithium-oxygen is possibly more correct, both seem to be valid usage. [1] - https://news.mit.edu/2016/new-lithium-oxygen-battery-greatly-improves-energy-efficiency-longevity-0725 https://news.mit.edu/2016/new-lithium-oxygen-battery-greatly... [2] - http://www.anl.gov/cnm/articles/lithium-air-battery-based-lithium-superoxide http://www.anl.gov/cnm/articles/lithium-air-battery-based-li...
- tim333 10y agoThe ANL only has "air" in the title "A Lithium-Air Battery Based on Lithium Superoxide" which you could read as an abbreviation of "a Lithium-Air like battery".
- Animats 10y agoRight. This doesn't need iridium, and may be more cost-effective. The MIT paper has more useful info. The materials used were only lithium, cobalt, iron, and potassium. All of those are abundant. They claim the battery is stable during overcharging, and only loses 1-2% of capacity in 130 cycles. If this is real, it's a big deal.