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>"Both experiment and calculation seem to indicate that water confined by solid walls to tiny regions of space, whose size is comparable to that of a few hundre
by Intermernet 11y ago
>"Both experiment and calculation seem to indicate that water confined by solid walls to tiny regions of space, whose size is comparable to that of a few hundred molecules, begins to exhibit quantum mechanical effects, including delocalization and quantum coherence."
Sounds like a possible source of random entropy for crypto :-) I did the Wolfram Alpha query[1] and it turns out that 100 molecules of water has a volume of 2.992 yL (yoctoliters, 10^-24 L). I didn't think we were up to yocto-technology yet! The paper that seems to describe this is called "Evidence of a new quantum state of nano-confined water"[2] so I have a feeling that "a few hundred molecules" may be a few orders of magnitude out.
From the paper:
"We find that in water confined on scales of 20˚A, this wave function responds to the
details of the confinement, corresponds to a strongly anharmonic local potential, shows evidence
in some cases of coherent delocalization in double wells, and involves changes in zero point kinetic
energy of the protons from -40 to +120 meV difference from that of bulk water at room temperature.
This behavior appears to be a generic feature of nanoscale confinement."
It's a really interesting paper. (although I had to do a lot of Wikipedia searches on certain terminology!)
[1]: http://www.wolframalpha.com/input/?i=volume+of+100+molecules+of+water http://www.wolframalpha.com/input/?i=volume+of+100+molecules...
[2]: http://arxiv.org/abs/1101.4994 http://arxiv.org/abs/1101.4994
- yread 11y agoI don't think yoctoliters necessarily rule out nanoscale, as the Wolfram page helpfully points out: Edge length of a cube of that volume is 1.4 nm